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Carbonyltris(triphenylphosphine)rhodium(I) hydride Structure

Carbonyltris(triphenylphosphine)rhodium(I) hydride

Chemical Properties

Melting point 150 °C (dec.) (lit.)
Density  1.33
vapor pressure  0Pa at 25℃
storage temp.  Keep in dark place,Inert atmosphere,2-8°C
solubility  Soluble in hydrocarbons (e.g. benzene and toluene) with dissociation of phosphine ligands
form  crystal
color  light yellow
Sensitive  Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Merck  14,9758
Exposure limits ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3
InChIKey CEKFIOLKXHVOKA-UHFFFAOYSA-N
CAS DataBase Reference 17185-29-4(CAS DataBase Reference)
NIST Chemistry Reference carbonyl(hydrido)tris(triphenylphosphine)rhodium(17185-29-4)
EPA Substance Registry System Rhodium, carbonylhydrotris(triphenylphosphine)-, (TB-5-23)- (17185-29-4)

Safety Information

Hazard Codes  T
Risk Statements  23/24/25
Safety Statements  36/37/39-45-36/37
RIDADR  UN 2811 6.1/PG 2
WGK Germany  1
10-23
TSCA  Yes
HazardClass  4.3
PackingGroup  III
HS Code  28439000

MSDS

Usage And Synthesis

Preparation Products And Raw materials

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