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Tris(triphenylphosphine)rhodiu Structure

Tris(triphenylphosphine)rhodiu

Chemical Properties

Melting point 245-250 °C (dec.)
Boiling point >170°C
Density  1.363; d 1.379
vapor pressure  0Pa at 25℃
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
solubility  Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution
form  Crystalline Powder
color  Red-brown to maroon
Water Solubility  insoluble
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
Sensitive  air sensitive
Merck  14,9758
BRN  4581440
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey QEYYHUJFSQCTAE-UHFFFAOYSA-M
LogP 5.69 at 20℃
CAS DataBase Reference 14694-95-2(CAS DataBase Reference)
NIST Chemistry Reference chlorotris(triphenylphosphine)rhodium(14694-95-2)
EPA Substance Registry System Rhodium, chlorotris(triphenylphosphine)-, (SP-4-2)- (14694-95-2)

Safety Information

Hazard Codes  C,Xi
Risk Statements  34-36/38
Safety Statements  22-24/25-37/39-28A-26-15-45-36/37/39
RIDADR  1759
WGK Germany  1
8-10-23
TSCA  Yes
HS Code  28439090

MSDS

Usage And Synthesis

Preparation Products And Raw materials

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