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网站主页CAS数据库列表 86-73-7更多图谱芴(86-73-7)红外图谱(IR1)

产品名称

CAS号86-73-7

分子式C13H10

分子量166.22

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  • Mass

    MS-NW-1806          
    fluorene
    C13H10              (Mass of molecular ion:    166)
    

       Source Temperature: 240 °C
       Sample Temperature: 180 °C
       Reservoir, 75 eV
    

          39.0       3.0
          50.0       2.0
          51.0       2.3
          62.0       2.7
          63.0       6.0
          69.5       6.0
          74.0       2.7
          75.0       2.1
          81.0       2.0
          81.5       4.7
          82.0       8.2
          82.5      12.4
          83.0       8.0
          83.5       1.0
          86.0       2.1
          87.0       2.9
          88.0       1.0
          89.0       2.5
          98.0       1.1
         113.0       2.0
         115.0       4.6
         137.0       1.2
         138.0       1.1
         139.0       8.1
         140.0       1.0
         162.0       1.5
         163.0      11.8
         164.0       9.9
         165.0      84.5
         166.0     100.0
         167.0      14.1
         168.0       2.5
    

parameter in cyclohexane

parameter in CDCl3

400 MHz in CDCl3

parameter in CCl4

parameter in acetone-d6


  • 1H NMR 300 MHz
    C13 H10 0.602 M in cyclohexane
    fluorene
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 7.352 D(B) 7.133 D(C) 7.207 D(D) 7.615 J(A,B) 7.76 J(A,C) 1.07 J(A,D) 0.86 J(B,C) 7.62 J(B,D) 1.12 J(C,D) 7.64 D(E) 3.70 DOURIS,J. & MATHIEU,A. BULL.SOC.CHIM.FR. 1971, 3365

         Hz     ppm     Int.
    

       2289.39   7.631    149
       2288.51   7.628    192
       2288.14   7.627    194
       2287.41   7.625    161
       2282.01   7.607    163
       2280.88   7.603    243
       2279.85   7.599    172
       2210.70   7.369    139
       2209.57   7.365    196
       2208.50   7.362    140
       2203.07   7.344    181
       2201.97   7.340    236
       2201.02   7.337    179
       2170.79   7.236    100
       2169.58   7.232    110
       2163.24   7.211    258
       2161.99   7.207    254
       2155.79   7.186    192
       2154.47   7.182    164
       2147.24   7.157    203
       2145.96   7.153    211
       2139.69   7.132    255
       2138.40   7.128    241
       2132.06   7.107     90
       2130.85   7.103     83
       1109.98   3.700   1000
    


  • 1H NMR 300 MHz
    C13 H10 0.991 M in CDCl3
    fluorene
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 7.447 D(B) 7.221 D(C) 7.294 D(D) 7.705 J(A,B) 7.77 J(A,C) 1.08 J(A,D) 0.76 J(B,C) 7.61 J(B,D) 1.16 J(C,D) 7.61 D(E) 3.79 DOURIS,J. & MATHIEU,A. BULL.SOC.CHIM.FR. 1971, 3365

         Hz     ppm     Int.
    

       2316.34   7.721    152
       2315.61   7.719    182
       2315.02   7.717    187
       2314.40   7.715    166
       2309.00   7.697    167
       2308.12   7.694    210
       2307.68   7.692    212
       2306.91   7.690    177
       2239.09   7.464    148
       2238.35   7.461    182
       2237.95   7.460    183
       2237.03   7.457    143
       2231.50   7.438    189
       2230.87   7.436    220
       2230.32   7.434    224
       2229.59   7.432    186
       2196.87   7.323     99
       2195.66   7.319    109
       2189.31   7.298    254
       2188.10   7.294    256
       2181.90   7.273    193
       2180.58   7.269    165
       2173.68   7.246    202
       2172.33   7.241    210
       2166.09   7.220    255
       2164.81   7.216    241
       2158.50   7.195     90
       2157.25   7.191     82
       1137.01   3.790   1000
    


  • 1H NMR 399.65 MHz
    C13 H10 1.60 mg : 0.5 ml CDCl3
    fluorene
    ChemicalStructure
        Assign.     Shift(ppm)
    A 7.783 B 7.536 C 7.367 D 7.297 E 3.889

         Hz     ppm     Int.
    

       3114.62   7.794    535
       3111.08   7.785     63
       3107.06   7.775    597
       3016.48   7.548    412
       3015.63   7.546    493
       3014.53   7.543    361
       3012.21   7.538     66
       3009.03   7.530    480
       3008.30   7.528    558
       3007.08   7.525    408
       3004.52   7.518     49
       2952.76   7.389    250
       2952.27   7.388    228
       2951.66   7.386    222
       2949.34   7.380     57
       2948.12   7.377     55
       2945.31   7.370    574
       2944.82   7.369    517
       2944.21   7.367    499
       2941.53   7.361     59
       2940.80   7.359     59
       2937.87   7.352    386
       2937.38   7.350    335
       2936.65   7.349    311
       2923.10   7.315    528
       2921.88   7.312    520
       2919.92   7.307     51
       2919.31   7.305     52
       2918.46   7.303     59
       2917.85   7.302     71
       2915.77   7.296    745
       2914.55   7.293    690
       2911.87   7.287     50
       2910.52   7.283     48
       2908.33   7.278    296
       2907.10   7.275    262
       1554.44   3.890   1000
    


  • 1H NMR 300 MHz
    C13 H10 0.980 M in CCl4
    fluorene
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 7.349 D(B) 7.135 D(C) 7.208 D(D) 7.605 J(A,B) 7.71 J(A,C) 1.02 J(A,D) 0.77 J(B,C) 7.53 J(B,D) 1.13 J(C,D) 7.67 D(E) 3.70 DOURIS,J. & MATHIEU,A. BULL.SOC.CHIM.FR. 1971, 3365

         Hz     ppm     Int.
    

       2286.38   7.621    152
       2285.61   7.619    186
       2285.09   7.617    190
       2284.47   7.615    166
       2278.97   7.597    166
       2277.72   7.592    224
       2276.91   7.590    179
       2209.68   7.366    144
       2208.65   7.362    199
       2207.66   7.359    143
       2202.12   7.340    191
       2201.46   7.338    226
       2201.02   7.337    231
       2200.25   7.334    187
       2171.01   7.237    100
       2169.84   7.233    111
       2163.53   7.212    266
       2162.32   7.208    260
       2156.08   7.187    193
       2154.80   7.183    165
       2147.79   7.159    203
       2146.47   7.155    211
       2140.27   7.134    255
       2138.99   7.130    243
       2132.75   7.109     89
       2131.51   7.105     82
       1109.98   3.700   1000
    


  • 1H NMR 300 MHz
    C13 H10 1.005 M in acetone-d6
    fluorene
    ChemicalStructure
        Parameter     ppm  Hz
    D(A) 7.501 D(B) 7.254 D(C) 7.324 D(D) 7.792 J(A,B) 7.79 J(A,C) 1.09 J(A,D) 0.81 J(B,C) 7.47 J(B,D) 1.17 J(C,D) 7.53 D(E) 3.81 DOURIS,J. & MATHIEU,A. BULL.SOC.CHIM.FR. 1971, 3365

         Hz     ppm     Int.
    

       2342.42   7.808    150
       2341.60   7.805    184
       2341.08   7.804    188
       2340.41   7.801    163
       2335.19   7.784    162
       2333.88   7.780    217
       2333.02   7.777    172
       2255.31   7.518    146
       2254.19   7.514    186
       2253.18   7.511    142
       2247.70   7.492    187
       2247.07   7.490    216
       2246.54   7.488    218
       2245.69   7.486    179
       2205.78   7.353     97
       2204.55   7.348    108
       2198.36   7.328    255
       2197.09   7.324    257
       2191.05   7.303    195
       2189.71   7.299    168
       2183.56   7.279    201
       2182.18   7.274    210
       2175.99   7.253    242
       2174.64   7.249    242
       2168.45   7.228     90
       2167.19   7.224     82
       1142.98   3.810   1000
    

in CDCl3



CCl4 solution



KBr disc



nujol mull



4880 A,200 M,powder