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Synthesis of Silicon tetrachloride

Jan 7，2022

Silicon tetrachloride or tetrachlorosilane is the inorganic compound with the formula SiCl4. It is a colourless volatile liquid that fumes in air. It is used to produce high purity silicon and silica for commercial applications.

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Synthesis

Silicon tetrachloride (SiCl4) can be manufactured by chlorination of silicon compounds such as ferrosilicon or silicon carbide, or by heating silicon dioxide and carbon in a stream of chlorine. It can also be obtained as a by-product in the production of zirconium tetrachloride, and in the past substantial quantities were produced by this route, which in recent decades has lost importance owing to the reduced demand for zirconium in nuclear facilities. Nowadays, industrial silicon tetrachloride is produced either by direct reaction of hydrogen chloride with silicon – this product mainly being employed as an intermediate in fumed silica production – or as the by-product of the production of silane for the microelectronics industry by disproportionation of trichlorosilane.

Property

Silicon tetrachloride is a colorless, noninflammable, volatile liquid with a pungent, suffocating odor. It fumes in air and is corrosive to metals and tissues in the presence of moisture. In experiments at Argonne National Laboratory in which it was mixed with water and stirred under room conditions, about 35% of the theoretical yield of HCl evolved as a gas in the first minute. It also reacts very rapidly with alcohols, primary and secondary amines, ammonia, and other compounds containing active hydrogen atoms. Thermal decomposition or burning may produce dense white clouds of silicon oxide particles and hydrogen chloride.

Environmental Fate

Silicon tetrachloride is a by-product in the production of polysilicon, the key component of sunlight-capturing wafers in solar energy panels, and for each ton of polysilicon produced, at least four tons of silicon tetrachloride liquid waste are generated. Pollution by silicon tetrachloride has been reported in China, associated with the increased demand for photovoltaic cells that has been stimulated by subsidy programs.

Studies of rats subjected to acute inhalation of 10 structurally similar chlorosilanes, including tetrachlorosilane, suggest that the acute toxicity of chlorosilanes is largely due to the hydrogen chloride hydrolysis product. The observed effects were similar to those of HCl inhalation both qualitatively (clinical signs) and quantitatively (molar equivalents of hydrogen chloride at the atmospheric LC50).

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